Evaluation of extract of neem tree (Azadirachta indica) as inhibitor of corrosion in saline medium
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- Submitted: January 26, 2016
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Published: February 26, 2018
Abstract
The inhibition efficiency of corrosion of the extract of neem leaves (Azadirachta indica) on carbon steel and aluminum was evaluated in contact with a sodium chloride and sodium sulfate solution, both at 3.5% p/v. Corrosion speed was determined and it was found that the Neem extract, at a lower concentration, reached better efficiencies on carbon steel in sodium chloride with 78% efficiency using 5% of the extract; concerning the aluminum, the efficiency values reached were low. Besides, through the adjustment to the Langmuir’s isotherms, it was possible to determine that the nem extract was adsorbed spontaneously on the surface of carbon steel and allowed to delay the corrosive process when reaching inhibition efficiencies of 90%. Results of this research allow establishing that the neem extract has a high potential as corrosion inhibitor to be applied in the industry as corrosion preventive medium.References
[1] H. Uhlig y R. Revie. Corrosion and corrosion control: an introduction to corrosion, en Science and engineering, 4a ed., New Jersey: John Wiley & Sons, Inc., Publication, 2008, 513 p.
[2] N. Huynh. “The inhibition of copper corrosion in aqueous environments heterocyclic compounds”. Tesis de doctorado ÁREA. Universidad Tecnológica de Queensland, 2004, 99 p.
[3] S. Ahmad. “Reinforcement corrosion in concrete structures, its monitoring and service life prediction––a review”. Cement and Concrete Composites, Vol. 25, pp. 459-471, 2003.
[4] L. Godínez, Y. Meas, R. Ortega-Borges y A. Corona. “Los inhibidores de corrosión”. Revista de Metalurgia, Vol. 39, N.° 2, pp. 140-158, 2003.
[5] V. S. Sastri, (2011). “Green CorrosionInhibitors: Theory and Practice”. Canada: John Wiley & Sons, Inc., Publication, 2011, 328 p.
[6] M. Quraishi, I. Faroogi y P. Saini. “Investigation of Some Green Compounds as Corrosion and Scale Inhibitors for Cooling Systems”.Journal Corrosion, Vol. 55, pp. 493-496, 1999.
[7] A. El-Etre y M. Abdallah.“Natural honey as corrosion inhibitor for metals and alloys”. II. C-steel in high saline water. Corrosion Science, Vol. 42, pp. 731-733, 2000.
[8] K. Orubite y N. Oforka. “Inhibition of the corrosion of mild steel in hydrochloric acid solutions by the extracts of leaves of Nypa fruticans Wurmb”.Materials Letters, Vol. 58, pp. 1768- 1772, 2004.
[9] P. Okafor, M. Ikpi, E. Ebemso, U. Ekpe y S. Umoren.“Inhibitory action of Phyllanthusamarus extracts on the corrosion of mild steel in acidic media”. CorrosionScience, Vol. 50, pp. 2310-2317, 2008.
[10] A. Satapathy, G. Gunasekaran, S. Sahoo, A. Kumar y P.Rodrigues. “Corrosion inhibition by Justiciagendarussa plant extract in hydrochloric acid solution”. Corrosion Science, Vol. 51, pp. 2848–2856, 2009.
[11] S. Kumar, S. Arora, M. Sharma, P. Arora y S. Mathur. “Synergistic effect of Calotropis plant in controlling corrosion of mild steel in basic solution”.Journal of the Chilean Chemical Society, Vol. 54, pp. 83-88, 2009.
[12] D. Prabhu, y P.Rao. Coriandrumsativum L. - A novel green inhibitor for the corrosion inhibition of aluminium in 1.0 M phosphoric acid solution. Journal of Environmental Chemical Engineering, 1, pp. 676–683, 2013.
[13] M. Berrocal, E. Altamiranda. “Estudio de la eficiencia de inhibidores de corrosión a partir de extractos vegetales”. Tesis de pregrado. Universidad de Cartagena, 2013, 101 p.
[14] J. Cifuentes, M. Torres y M. Frías. El océano y sus recursos II. Las ciencias del mar: oceanografía geológica y oceanografía química, 3a ed., México: Editorial Fondo de Cultura Económica, SEP, CONACyT, 1986, 170 p.
[15] S.Garai,S.Garai, P.Jaisankar, J.K. Singh, y A. Elango. A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution. Corrosion Science, Vol. 60, pp. 193–204, 2012.
[16] O. Abiola, E. Odin, D. Olowoyo y T.Adeloye. “Gossipiumhirsutuml. Extract as green corrosion inhibitor for Aluminum in HCl solution”. Bulletin of the Chemical Society of Ethiopia, Vol. 45, pp. 475-480, 2011.
[17] R. Silveira, E. Cassel y D. Schermann. “Black Wattle Tannin as Steel Corrosion Inhibitor”. ISRN Corrosion, Vol. 2012, pp. 1-9, 2012.
[18] A. Nahl´e, I. Abu-Abdoun, I. Abdel-Rahman, y M. Al-Khayat. “UAE Neem Extract as a Corrosion Inhibitor for Carbon Steel in HCl Solution”. International Journal of Corrosion, Vol. 2010, pp. 1-9, 2010.
[19] B. Amitha y J. Bharathi.“Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview”. International Journal of Corrosion, Vol. 2012, pp. 1-15, 2012.
[20] D. Skoog, D. West, F. James Holler y S. Crouch. Fundamentos de Química Analítica. 8va ed., México: S.A. Ediciones Paraninfo, 2005, 1196 p.
[21] A. El-Etre. “Inhibition of aluminum corrosion using Opuntia extract”. Corrosion Science. Vol. 45, pp. 2485–2495, 2003.
[22] Z. Dan, I.Mutob, y N. Harab. “Effects of environmental factors on atmospheric corrosion of aluminium and its alloys under constant dew point conditions”.Corrosion Science, vol. 57, pp. 22-29, 2012.
[23] J. Ávila y J. Genescá. Más allá de la herrumbre I. 1a ed., México: Fondo De Cultura Económica, S. A. de C.V., 1987, pp. 50-85.
[24] A. Balbo, A. Frignani, V. Grassi y F.Zucchi.“Corrosion inhibition by anionic surfactants of AA2198 Li-containingaluminium alloy in chloride solutions”. Corrosion Science, Vol. 73, pp. 80-88, 2013.
[25] R. Touri, M. Cenoui, M. Bakri y M. Touhami.“Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water”.Corrosion Science, Vol. 50, pp.1530-1537, 2008.
[26] G. Quartarone, L. Ronchin, A. Vavasori, C. Tortato y L. Bonaldo. “Inhibitive action of gramine towards corrosion of mild Steel in deaerated 1.0 M hydrochloric acid solutions”. Corrosion Science, Vol. 64, pp. 82-89, 2012.
[27] A. Bribria, M. Tabyaouia, B. Tabyaouia, H. Attaric y F. Bentissc. “The use of Euphorbia falcata extract as eco-friendly corrosion inhibitor of carbon steel in hydrochloric acid solution”. Materials Chemistry and Physics, Vol. 141, pp. 240-247, 2013.
[28] L. Lia, X. Zhanga, J. Leia, J. Hea, S. Zhanga y F. Panb. “Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel”. Corrosion Science, Vol. 63, pp. 82-90, 2012.
[29] M. Hussin y M. Kassim.“The corrosion inhibition and adsorption behavior of Uncariagambirextract on mild steel in 1 M HCl”. Materials Chemistry and Physics, Vol. 125, pp. 461-468, 2011.
[30] J. Condon. Surface Area and Porosity Determinations by Physisorption: Measurements and Theory. 1a Ed., Harriman: Elsevier, 2006, pp. 2-10.
[31] G. Pinder y W. Gray. Essentials of Multiphase Flow in Porous Media. 1a ed., New Jersey: John Wiley & Sons, Inc., Publication, 2008, pp. 180-186.
[2] N. Huynh. “The inhibition of copper corrosion in aqueous environments heterocyclic compounds”. Tesis de doctorado ÁREA. Universidad Tecnológica de Queensland, 2004, 99 p.
[3] S. Ahmad. “Reinforcement corrosion in concrete structures, its monitoring and service life prediction––a review”. Cement and Concrete Composites, Vol. 25, pp. 459-471, 2003.
[4] L. Godínez, Y. Meas, R. Ortega-Borges y A. Corona. “Los inhibidores de corrosión”. Revista de Metalurgia, Vol. 39, N.° 2, pp. 140-158, 2003.
[5] V. S. Sastri, (2011). “Green CorrosionInhibitors: Theory and Practice”. Canada: John Wiley & Sons, Inc., Publication, 2011, 328 p.
[6] M. Quraishi, I. Faroogi y P. Saini. “Investigation of Some Green Compounds as Corrosion and Scale Inhibitors for Cooling Systems”.Journal Corrosion, Vol. 55, pp. 493-496, 1999.
[7] A. El-Etre y M. Abdallah.“Natural honey as corrosion inhibitor for metals and alloys”. II. C-steel in high saline water. Corrosion Science, Vol. 42, pp. 731-733, 2000.
[8] K. Orubite y N. Oforka. “Inhibition of the corrosion of mild steel in hydrochloric acid solutions by the extracts of leaves of Nypa fruticans Wurmb”.Materials Letters, Vol. 58, pp. 1768- 1772, 2004.
[9] P. Okafor, M. Ikpi, E. Ebemso, U. Ekpe y S. Umoren.“Inhibitory action of Phyllanthusamarus extracts on the corrosion of mild steel in acidic media”. CorrosionScience, Vol. 50, pp. 2310-2317, 2008.
[10] A. Satapathy, G. Gunasekaran, S. Sahoo, A. Kumar y P.Rodrigues. “Corrosion inhibition by Justiciagendarussa plant extract in hydrochloric acid solution”. Corrosion Science, Vol. 51, pp. 2848–2856, 2009.
[11] S. Kumar, S. Arora, M. Sharma, P. Arora y S. Mathur. “Synergistic effect of Calotropis plant in controlling corrosion of mild steel in basic solution”.Journal of the Chilean Chemical Society, Vol. 54, pp. 83-88, 2009.
[12] D. Prabhu, y P.Rao. Coriandrumsativum L. - A novel green inhibitor for the corrosion inhibition of aluminium in 1.0 M phosphoric acid solution. Journal of Environmental Chemical Engineering, 1, pp. 676–683, 2013.
[13] M. Berrocal, E. Altamiranda. “Estudio de la eficiencia de inhibidores de corrosión a partir de extractos vegetales”. Tesis de pregrado. Universidad de Cartagena, 2013, 101 p.
[14] J. Cifuentes, M. Torres y M. Frías. El océano y sus recursos II. Las ciencias del mar: oceanografía geológica y oceanografía química, 3a ed., México: Editorial Fondo de Cultura Económica, SEP, CONACyT, 1986, 170 p.
[15] S.Garai,S.Garai, P.Jaisankar, J.K. Singh, y A. Elango. A comprehensive study on crude methanolic extract of Artemisia pallens (Asteraceae) and its active component as effective corrosion inhibitors of mild steel in acid solution. Corrosion Science, Vol. 60, pp. 193–204, 2012.
[16] O. Abiola, E. Odin, D. Olowoyo y T.Adeloye. “Gossipiumhirsutuml. Extract as green corrosion inhibitor for Aluminum in HCl solution”. Bulletin of the Chemical Society of Ethiopia, Vol. 45, pp. 475-480, 2011.
[17] R. Silveira, E. Cassel y D. Schermann. “Black Wattle Tannin as Steel Corrosion Inhibitor”. ISRN Corrosion, Vol. 2012, pp. 1-9, 2012.
[18] A. Nahl´e, I. Abu-Abdoun, I. Abdel-Rahman, y M. Al-Khayat. “UAE Neem Extract as a Corrosion Inhibitor for Carbon Steel in HCl Solution”. International Journal of Corrosion, Vol. 2010, pp. 1-9, 2010.
[19] B. Amitha y J. Bharathi.“Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview”. International Journal of Corrosion, Vol. 2012, pp. 1-15, 2012.
[20] D. Skoog, D. West, F. James Holler y S. Crouch. Fundamentos de Química Analítica. 8va ed., México: S.A. Ediciones Paraninfo, 2005, 1196 p.
[21] A. El-Etre. “Inhibition of aluminum corrosion using Opuntia extract”. Corrosion Science. Vol. 45, pp. 2485–2495, 2003.
[22] Z. Dan, I.Mutob, y N. Harab. “Effects of environmental factors on atmospheric corrosion of aluminium and its alloys under constant dew point conditions”.Corrosion Science, vol. 57, pp. 22-29, 2012.
[23] J. Ávila y J. Genescá. Más allá de la herrumbre I. 1a ed., México: Fondo De Cultura Económica, S. A. de C.V., 1987, pp. 50-85.
[24] A. Balbo, A. Frignani, V. Grassi y F.Zucchi.“Corrosion inhibition by anionic surfactants of AA2198 Li-containingaluminium alloy in chloride solutions”. Corrosion Science, Vol. 73, pp. 80-88, 2013.
[25] R. Touri, M. Cenoui, M. Bakri y M. Touhami.“Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water”.Corrosion Science, Vol. 50, pp.1530-1537, 2008.
[26] G. Quartarone, L. Ronchin, A. Vavasori, C. Tortato y L. Bonaldo. “Inhibitive action of gramine towards corrosion of mild Steel in deaerated 1.0 M hydrochloric acid solutions”. Corrosion Science, Vol. 64, pp. 82-89, 2012.
[27] A. Bribria, M. Tabyaouia, B. Tabyaouia, H. Attaric y F. Bentissc. “The use of Euphorbia falcata extract as eco-friendly corrosion inhibitor of carbon steel in hydrochloric acid solution”. Materials Chemistry and Physics, Vol. 141, pp. 240-247, 2013.
[28] L. Lia, X. Zhanga, J. Leia, J. Hea, S. Zhanga y F. Panb. “Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel”. Corrosion Science, Vol. 63, pp. 82-90, 2012.
[29] M. Hussin y M. Kassim.“The corrosion inhibition and adsorption behavior of Uncariagambirextract on mild steel in 1 M HCl”. Materials Chemistry and Physics, Vol. 125, pp. 461-468, 2011.
[30] J. Condon. Surface Area and Porosity Determinations by Physisorption: Measurements and Theory. 1a Ed., Harriman: Elsevier, 2006, pp. 2-10.
[31] G. Pinder y W. Gray. Essentials of Multiphase Flow in Porous Media. 1a ed., New Jersey: John Wiley & Sons, Inc., Publication, 2008, pp. 180-186.
How to Cite
Meza-Castellar, P., Tejada-Tovar, C., Loaiza-Fernández, S., Vidales-Manrique, A., & Villabona Ortiz, Ángel. (2018). Evaluation of extract of neem tree (Azadirachta indica) as inhibitor of corrosion in saline medium. Revista Ingenierías Universidad De Medellín, 16(31), 15-31. https://doi.org/10.22395/rium.v16n31a1
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